Can you book a flight using Qantas points directly with British Airways, and not through Qantas?
No. If you’re using Qantas points, you need to book through Qantas. If you’re looking at a flight that’s showing on BA but not on Qantas, you’ll need to give Qantas a call.
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To add, I believe BAEC members have priority (see more award seats) on some flights particularly their own BA flights. If you verify via a third OneWorld member airline that you can see an award space that Qantas can’t see, it gives you more justification/confidence that Qantas should be able to access the same award seats.